Study of heat release rates of mining vehicles in underground hard rock mines

Lu, Y. (2010). Experimental Studies on CO₂ Absorption in Hollow Fiber Membrane Contactor. Licentiatavhandling i energi- och miljöteknik vid Mälardalens högskola.

Abstract

Membrane gas absorption technology is considered as one of the promising alternatives to conventional techniques for CO₂ separation from the flue gas of fossil fuels combustion. As a hybrid approach of chemical absorption and membrane separation, it may offer a number of important features, including operational flexibility, compact structure, linear scale up and predictable performance. The main challenge is the additional membrane mass transfer resistance, especially when this resistance increases due to the absorbent intruding into the membrane pores.

In this thesis, the experimental was set up to investigate how the operating parameters affect the absorption performance when using absorbent in hollow fiber contactor, and to obtain the optimal range of operation parameters for the designated membrane gas absorption system . During 20 days’ continuous experiment, we observed that the CO₂ mass transfer rate decreases significantly following the operating time, which is attributed to the increase of membrane mass transfer resistance resulting from partial membrane wetting.

To better understand the wetting evolution mechanism, the immersion experiments were carried out to assume that the membrane fibers immersed in the absorbents would undergo similar exposure as those used in the membrane contactor. Various membrane characterization methods were used to illustrate the wetting process before and after the membrane fibers were exposed to the absorbents. The characterization results showed that the absorbent molecules diffuse into the polypropylene (PP) polymer during the contact with the membrane, resulting in the swelling of the membrane. In addition, the effects of operating parameters such as immersion time, CO₂ loading, as well as absorbent type on the membrane wetting were investigated in detail. Finally, based on the analysis results, methods to smooth the membrane wetting were discussed. It was suggested that improving the hydrophobicity of PP membrane by surface modification may be an effective way to improve the membrane long-term performance.

Modification of the polypropylene membrane by depositing a rough layer of PP was carried out in order to improve the non-wettability of membrane. The comparison of long-term CO₂ absorption performance by PP membranes before and after modification proves that the modified polypropylene membranes retained higher hydrophobicity than the untreated polypropylene membrane. Therefore modification is likely to be more suitable for use in membrane gas absorption contactors for CO₂ separation, particularly over long operation time.